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Cover
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Title Page
1. Copyright
List of Contributors
1. Chapter 1: Introduction
2. Chapter 2: Network Topology
  1. 2.1 Introduction
  2. 2.2 Crystal Structures and MOFs Regarded as Nets
  3. 2.3 Some Introductory Remarks about Graphs, Topology, and Symmetry
  4. 2.4 Nomenclature of and Symbols for Nets – or What Does 4.4.4.4.4.4.4.4.4.4.4.4.*.*.* Mean?
  5. 2.5 Characterization of Nets in the Spirit of the RCSR
  6. 2.6 Derived Nets: Relationships Between Nets
  7. 2.7 Simplification of MOFs and Linkers or the Famous Case “4-c versus 2 Times 3-c”
  8. 2.8 A Very Short Survey on Common and Not So Common Nets: The Minimal Transitivity Principle
  9. 2.9 Summary and Conclusions
  10. Acknowledgment
  11. References
Part I: MOF Chemistry of Metallic Clusters and Other Nodes
1. Chapter 3: Reticular Chemistry of Metal–Organic Frameworks Composed of Copper and Zinc Metal Oxide Secondary Building Units as Nodes
  1. 3.1 Introduction
  2. 3.2 Secondary Building Units (SBUs): The Design Principles of MOFs
  3. 3.3 Points of Extension
  4. 3.4 Concluding Remarks
  5. Acknowledgment
  6. References
2. Chapter 4: Alkaline Earth Metal-Based Metal–Organic Frameworks: Synthesis, Properties, and Applications
  1. 4.1 Introduction
  2. 4.2 Synthesis
  3. 4.3 Structures
  4. 4.4 Properties and Applications
  5. 4.5 Conclusions and Outlook
  6. Acknowledgments
  7. References
3. Chapter 5: Synthesis, Structure, and Selected Properties of Aluminum-, Gallium-, and Indium-Based Metal–Organic Frameworks
  1. 5.1 Introduction
  2. 5.2 Properties of Al³⁺, Ga³⁺, and In³⁺ ions
  3. 5.3 Synthesis and Characterization of G13-MOFs
  4. 5.4 Prevalent Framework Structures and Inorganic Building Units in G13-MOFs
  5. 5.5 Selected G13-MOFs
  6. 5.6 Selected Aspects of G13-MOFs
  7. References
4. Chapter 6: Group 4 Metals as Secondary Building Units: Ti, Zr, and Hf-based MOFs
  1. 6.1 Introduction
  2. 6.2 Zirconium-Based MOFs
  3. 6.3 Summary and Conclusions
  4. References
5. Chapter 7: Iron and Groups V- and VI-based MOFs
  1. 7.1 Introduction: The Chemistry in Solution
  2. 7.2 MOFs Based on Iron, Chromium, or Vanadium
  3. 7.3 MOFs Based on Nb, Ru, Mo, and W
  4. 7.4 Synthesis at the Nanoscale
  5. 7.5 Properties
  6. 7.6 Conclusion
  7. Acknowledgments
  8. References
6. Chapter 8: Platinum Group Metal–Organic Frameworks
  1. 8.1 Introduction
  2. 8.2 Single Node Frameworks
  3. 8.3 Metalloligands for the Construction of Mixed Metal–Organic Frameworks (M′MOFs)
  4. 8.4 Hofmann-Type MOFs
  5. 8.5 Coordination Polymers with Paddle-Wheel Metal Clusters
  6. 8.6 Summary and Conclusions
  7. References
7. Chapter 9: Group 3 Elements and Lanthanide Metals
  1. 9.1 Introduction
  2. 9.2 Chemistry and Structures of Group 3 and Lanthanide-Based MOFs
  3. 9.3 Electronic and Optical Properties of Group 3 and Lanthanide-Based MOFs
  4. 9.4 Summary and Conclusions
  5. References
Part II: Functional Linkers
1. Chapter 10: Extended Linkers for Ultrahigh Surface Area Metal–Organic Frameworks
  1. 10.1 Introduction
  2. 10.2 Brief Introduction of the History of Porous MOFs
  3. 10.3 General Synthetic Strategy for Extended Organic Linkers
  4. 10.4 Case Studies of Extended Linkers
  5. 10.5 Summary and Conclusions
  6. Acknowledgment
  7. References
2. Chapter 11: Porous Metal Azolate Frameworks
  1. 11.1 Introduction
  2. 11.2 Imidazolate Coordination Modes
  3. 11.3 Pyrazolate Coordination Modes
  4. 11.4 Triazolate Coordination Modes
  5. 11.5 Tetrazolate and Other Coordination Modes
  6. 11.6 Summary and Conclusions
  7. Acknowledgments
  8. References
3. Chapter 12: Functional Linkers for Catalysis
  1. 12.1 Introduction: MOF in Catalysis
  2. 12.2 Self-Assembled Frameworks
  3. 12.3 Postsynthetic Modification
  4. 12.4 Relevant and Accurate Characterizations as Key for the Design of MOF Catalyst
  5. References
4. Chapter 13: Chiral Linker Systems
  1. 13.1 Introduction
  2. 13.2 Section A: Classes of Chiral Linkers
  3. 13.3 Section B: Enantioselective Separation and Chromatography with Chiral MOFs
  4. 13.4 Summary and Conclusions
  5. References
5. Chapter 14: Functional Linkers for Electron-Conducting MOFs
  1. 14.1 Introduction
  2. 14.2 Methods for Measuring Electrical Properties
  3. 14.3 Linkers
  4. 14.4 Conclusion and Perspective
  5. Acknowledgments
  6. References
6. Chapter 15: Linkers with Optical Functionality
  1. 15.1 Linker Electronic Structure
  2. 15.2 Design Principles
  3. 15.3 Linkers for Light Harvesting
  4. 15.4 Bioimaging
  5. 15.5 Linkers for Chemical Sensing
  6. 15.6 Radiation Detection
  7. 15.7 Conclusions
  8. References
Part III: Special MOF Classes and Morphology Design of MOFs
1. Chapter 16: Nanoparticles
  1. 16.1 Introduction
  2. 16.2 Nanoparticles
  3. 16.3 Synthesis of MOF Nanoparticles
  4. 16.4 Engineering MOF Nanoparticles
  5. 16.5 Application of MOF Nanoparticles
  6. 16.6 Nanotoxicology
  7. 16.7 Summary and Conclusions
  8. Acknowledgments
  9. References
2. Chapter 17: SURMOFs: Liquid-Phase Epitaxy of Metal–Organic Frameworks on Surfaces
  1. 17.1 Introduction
  2. 17.2 Fabrication of Novel MOF Materials by LPE-Based Synthesis
  3. 17.3 Heterostructured SURMOFs (Hetero-SURMOFs)
  4. 17.4 Postsynthetic Modification of SURMOFs
  5. 17.5 SURMOFs as New Investigation Platform to Determine MOF Properties
  6. 17.6 Advanced Applications
  7. 17.7 Conclusion
  8. References
3. Chapter 18: Granulation and Shaping of Metal–Organic Frameworks
  1. 18.1 Introduction
  2. 18.2 Granulation
  3. 18.3 Spray Drying
  4. 18.4 Extrusion
  5. 18.5 Pressing
  6. 18.6 Summary
  7. Acknowledgments
  8. References
Part IV: Progress in Advanced Characterization of MOFs
1. Chapter 19: Adsorption Methodology
  1. 19.1 Introduction
  2. 19.2 Sample Preparation for Adsorption Measurements
  3. 19.3 Porosity Determination
  4. 19.4 Enthalpy of Adsorption and Isosteric Enthalpy of Adsorption
  5. 19.5 High Pressure Adsorption: Fundamentals and Practical Aspects
  6. 19.6 Summary and Conclusions
  7. References
2. Chapter 20: Nuclear Magnetic Resonance of Metal–Organic Frameworks (MOFs)
  1. 20.1 Solid-State NMR Spectroscopy: A Brief Introduction
  2. 20.2 Applications of Solid-State NMR Spectroscopy to Study the MOF Lattice
  3. 20.3 NMR Spectroscopic Studies of Host–Guest Interactions
  4. 20.4 Summary and Conclusions
  5. References
3. Chapter 21: Electron Paramagnetic Resonance
  1. 21.1 Introduction
  2. 21.2 EPR Spectroscopy
  3. 21.3 Applications of EPR in MOF Science
  4. 21.4 Conclusions
  5. References
4. Chapter 22: IR and Raman Spectroscopies Probing MOFs Structure, Defectivity, and Reactivity
  1. 22.1 Introduction
  2. 22.2 Raman and IR Spectroscopy to Check the Synthesis Product
  3. 22.3 Spectroscopic Monitoring of Gas Adsorption
  4. 22.4 Spectroscopic Monitoring of Catalytic Reactions
  5. 22.5 Conclusions
  6. References
5. Chapter 23: In Situ X-ray Diffraction and XAS Methods
  1. 23.1 Introduction
  2. 23.2 In Situ Diffraction Techniques
  3. 23.3 In Situ X-ray Absorption Spectroscopy on MOFs
  4. 23.4 Summary and Conclusions
  5. References
6. Chapter 24: In Situ Studies of the Crystallization of Metal–Organic Frameworks
  1. 24.1 Introduction
  2. 24.2 In Situ Diffraction
  3. 24.3 In Situ Studies Using Scattering and Spectroscopic Methods
  4. 24.4 Microscopy and Other Methods
  5. 24.5 Summary and Future Directions
  6. References
7. Chapter 25: Role of Molecular Simulations in the Field of MOFs
  1. 25.1 Introduction
  2. 25.2 Structure Solution of MOFs: An Indispensable Interplay Between Characterization and Modeling Tools
  3. 25.3 Structure Prediction of Novel MOFs: A Relatively Poor Success of the High-Throughput Computational Approach
  4. 25.4 Adsorption in MOFs: From Prediction Toward Understanding
  5. 25.5 Rationalization of the Adsorption Performances of MOFs: A Recent Evolving Field
  6. 25.6 Probing the Dynamics of Guests Confined in MOFs Using a Joint Experimental Modeling: A Success Story
  7. 25.7 New Computational Challenges
  8. Acknowledgments
  9. References
8. Chapter 26: Defects and Disorder in MOFs
  1. 26.1 Introduction
  2. 26.2 Defects in MOFs
  3. 26.3 Summary and Conclusions
  4. References
9. Appendix A: Appendix A: MOF Suppliers
10. Appendix A: Appendix B: Datasheets
  1. 2.1 Aluminum Fumarate (Basolite A520)
  2. 2.2 MIL-100(Al) (Material of Institute Lavoisier-100)
  3. 2.3 MIL-101(Cr) (Chromium(III) Terephthalate, Material of Institute Lavoisier-101)
  4. 2.4 HKUST-1 (Hong Kong University of Science and Technology-1)
  5. 2.5 ZIF-8 (Zeolitic Imidazolate Framework-8)
  6. 2.6 UiO-66 (Universitetet i Oslo 66, Zirconium Terephthalate)
  7. 2.7 DUT-67(Zr) (Dresden University of Technology-67)
11. Index
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